Angewandte Chemie International Edition · 2004 · 858 citations · 25 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryNanomaterialsNanotechnologyMetal Oxide NanomaterialsMetal OxidesNanocatalysisRedox ChemistryRedox-active MaterialsSurface OxidationCatalytic NanoparticlesCerium Oxide NanoparticlesCo OxidationMetal Oxide NanocatalystsMetal-catalyzed OxidationOxidationOxidation KineticsOxidation Thermodynamics
The smaller the better: Depositing gold on nanocrystalline particles of cerium oxide, instead of a regular cerium oxide support, increases the activity of the resulting catalyst by two orders of magnitude for the selective oxidation of CO to CO2, even in the presence of H2 (shown schematically).
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Low-Temperature Oxidation of CO over Gold Supported on TiO2, α-Fe2O3, and Co3O4
M. Haruta, Susumu Tsubota, Tetsuhiko Kobayashi et al. · Journal of Catalysis · 1993 · 2.2K citations
Geoffrey C. Bond, David T. Thompson · Catalysis Reviews · 1999 · 1.7K citations
Catalysis of Gold Nanoparticles Deposited on Metal Oxides
Masatake Haruta · CATTECH · 2002 · 1.1K citations