Two‐Dimensional Helix‐Bundle Formation of a Dynamic Helical Poly(phenylacetylene) with Achiral Pendant Groups on Graphite

Abstract

It all makes sense: A dynamically racemic helical polymer crystallizes on graphite upon exposure to an organic solvent vapor, resulting in two-dimensional helix-bundle formation. The enantiomeric right- and left-handed helical blocks separated by helical reversals can be directly visualized by AFM with molecular resolution. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z701546_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.