Molecular Transporter Between Polymer Platforms: Highly Efficient Chemoenzymatic Glycopeptide Synthesis by the Combined Use of Solid‐Phase and Water‐Soluble Polymer Supports

Abstract

The molecule standing at platform one …︁: Rapid glycopeptide synthesis is achieved with a heterobifunctional “molecular transporter” (see scheme), which interfaces two types of polymer platforms for combined chemical and enzymatic synthesis. This linker allows both chemoselective blotting and photoselective cleavage of the glycopeptides. Red: sugar residues; green: amino acid residues. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z463065_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.