Synthesis and Structure of Carbene‐Stabilized N‐Centered Cations [L₂N]⁺, [L₂NR]²⁺, [LNR₃]²⁺, and [L₃N]³⁺

Abstract

Crystallized! Mono-, di-, and tricationic amines that display unprecedented chemical environments around the central nitrogen atom have been structurally characterized. Cyclic voltammetry experiments and density functional calculations have been performed to gain insight into the electronic structure of these new compounds. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.