Fine Size Control of Platinum on Carbon Nanotubes: From Single Atoms to Clusters

Yong‐Tae Kim, Kazuyoshi Ohshima, Koichi Higashimine, Tomoya Uruga, Masaki Takata, Hiroyoshi Suematsu, Tadaoki Mitani

Angewandte Chemie International Edition · 2005 · 245 citations · 28 references

Concepts

Abstract

Bond formation between single Pt atoms and surface thiol groups is the result of the reduction of a Pt precursor in the presence of surface-thiolated carbon nanotubes. By setting the temperature of the following heat treatment, finely size-controlled and monodispersed Pt clusters were obtained from the dispersed single atoms (see picture).

References

28