Angewandte Chemie International Edition · 2005 · 245 citations · 28 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryNanomaterialsPhysical ChemistryCarbon NanotubesCluster ChemistryNanomaterial CharacterizationNanomaterials SynthesisNanotubesThermodynamics Of NanomaterialsControlled Size SynthesisNanoparticle Size EffectsNanotube Diameter ControlPlatinum CompoundsSize Control
Bond formation between single Pt atoms and surface thiol groups is the result of the reduction of a Pt precursor in the presence of surface-thiolated carbon nanotubes. By setting the temperature of the following heat treatment, finely size-controlled and monodispersed Pt clusters were obtained from the dispersed single atoms (see picture).
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