Reaction of the π-allyl groups of the dodecatrienylnickel complex with aldehydes, acetyl chloride, and allyl bromide - Concepedia

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Reaction of the π-allyl groups of the dodecatrienylnickel complex with aldehydes, acetyl chloride, and allyl bromide

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References

1972

Year

R. Baker, B. N. Blackett, R. C. Cookson, R. C. Cross, D. P. Madden

Journal of the Chemical Society Chemical Communications

Abstract

Acetaldehyde, acetyl chloride, and acrolein add to one of the π-allyl groups of dodecatrienylnickel (1) giving long chain organic compounds; in the presence of allyl bromide, addition to both π-allyl groups occurs giving products of increased chain length.