Direct Synthesis of 1,4‐Disubstituted‐5‐alumino‐1,2,3‐triazoles: Copper‐Catalyzed Cycloaddition of Organic Azides and Mixed Aluminum Acetylides

Abstract

Al together now: Aluminotriazoles are obtained in a fully chemo- and regioselective manner by a copper-catalyzed cycloaddition of organic azides with mixed-aluminum acetylides (see scheme). The carbonaluminum bond, which is unaffected by the first transformation, is still able to react further with different electrophiles. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.