Publication | Closed Access
First asymmetric SmI2-induced cross-coupling of Cr(CO)3 aromatic nitrone complexes with carbonyl compounds
26
Citations
9
References
2004
Year
Aromatic Nitrone ComplexesCarbonyl CompoundsChemical EngineeringCross-coupling ReactionEngineeringNatural SciencesExcellent YieldsCoordination ComplexOrganic ChemistryOrganometallic CatalysisMolecular ComplexQuantum ChemistryChemistryAsymmetric Smi2-induced Cross-couplingDiastereoselective Reaction AffordsBiomolecular Engineering
The SmI(2)-induced cross-coupling of Cr(CO)(3)-complexed nitrones with carbonyl compounds is described. This highly chemo- and diastereoselective reaction affords enantiopure [small beta]-amino alcohol complexes in excellent yields.
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