Recent Progress in Exploring Magnetocaloric Materials

TLDR

Magnetic refrigeration using the magnetocaloric effect is gaining interest for its high efficiency and environmental friendliness. This review focuses on recent progress in effective magnetocaloric materials, particularly LaFe₁₃₋ₓSiₓ alloys discovered by the authors. The authors review techniques for measuring MCE in first‑order transitions, strategies to reduce hysteresis, factors influencing magnetic exchange, and survey other notable MCE materials. LaFe₁₃₋ₓSiₓ alloys show large entropy changes near room temperature, and magnetic rare‑earth doping, interstitial atoms, and high pressure systematically improve MCE, supporting their use in ambient‑temperature magnetic refrigeration.

Abstract

Abstract The magnetic refrigeration technique based on the magnetocaloric effect (MCE) has attracted increasing interest because of its high efficiency and environment friendliness. In this article, our recent progress in exploring effective MCE materials is reviewed with emphasis on the MCE in the LaFe 13− x Si x based alloys discovered by us. These alloys show large entropy changes over a wide temperature range near room temperature. The effects of magnetic rare‐earth doping, interstitial atoms and high pressure on the MCE have been systematically studied. Special issues, such as appropriate approaches to determining the MCE associated with the first‐order magnetic transition, the depression of magnetic and thermal hysteresis, and the key factors determining the magnetic exchange in alloys of this kind, are discussed. The applicability of giant MCE materials to magnetic refrigeration near ambient temperature is evaluated. A brief review of other materials with significant MCE is also presented.