Synthesis and characterization of poly(sodium-p-styrenesulfonate)/modified SiO2 spherical brushes

Abstract

The multistep procedures for preparing novel anionic spherical polyelectrolyte brushes (ASPB) by grafting sodium-p-styrenesulfonate (SSS) from the surface of !-methacryloxypropyl trimethoxy-silane modified SiO 2 nanoparticles were demonstrated. The morphology of ASPB was characterized by Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM). The core radius R c and hydrodynamic radius R h of ASPB measured by Zeta Potential/Particle Sizer (ZLS) were ca. 50nm and (84.51) nm respectively. The percentage of grafting (PG%) of polyelectrolyte brushes was 4.3% investigated by Thermo-gravimetric analysis (TGA). Detailed characterizations on ASPB were performed by cleaving the grafts from the anchoring surface. The molecular weight (M w ) and polydispersity (M w /M n ) of brushes were 1.78810 3 g/mol and 1.6 respectively from Gel Permeation Chromatography (GPC) measurements. Moreover, R h and !-potential of ASPB in the presence of aqueous NaCl solutions of different concentrations were discussed.