Titanium‐Mediated Domino Radical Cyclization/β Elimination of Phosphine Oxides

Abstract

A phosphinoyl radical leaving group in the β position is a key feature of a new TiIII-mediated domino radical cyclization/β elimination reaction of vinylic phosphine oxides, which affords alkylidenepyrrolidines in good yields (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z460099_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.