Publication | Closed Access
Hybrid Molecular Materials Based on Covalently Linked Inorganic Polyoxometalates and Organic Conjugated Systems We thank the University of Missouri-Kansas City and Research Corporation for supporting this work.
107
Citations
0
References
2001
Year
EngineeringMolecule-based MaterialOrganic ChemistryChemistryOrganic Conjugated SystemsMo≡n BondMissouri-kansas CityOrganometallic CatalysisHybrid MaterialsPolymer ChemistryMaterials ScienceInorganic ChemistryHybrid Molecular MaterialsOrganic SegmentMolecular EngineeringOrganic Material ChemistryOrganic Conjugated SystemPolymer ScienceInorganic PolymerFunctional MaterialsPolymer HybridOrganic-inorganic Hybrid Material
The Mo≡N bond is conjugated with the organic segment in the novel molecular organic-inorganic hybrid materials that have been obtained by Pd-catalyzed coupling of an iodo-functionalized hexamolybdate anion and an alkyne (see scheme; Ar=4-methylphenyl,3-5-di(tert-butyl)phenyl). The interaction between the polyoxometalate cluster and the organic conjugated system is particularly apparent from the strong red-shifted absorption in the UV/Vis spectrum.