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A Novel Chainlike Heteropolyanion Formed by Keggin Units: Synthesis and Structure of (ET)<sub>8<i>n</i></sub>[PMnW<sub>11</sub>O<sub>39</sub>]<sub><i>n</i></sub> · 2<i>n</i>H<sub>2</sub>O
219
Citations
16
References
1995
Year
Materials ScienceInorganic ChemistryOrganic Material ChemistryEngineeringHeterocyclicKeggin UnitsPolymer ScienceUnits Pmnw11o39Organic ChemistryLocalized Magnetic MomentsMain Group ChemistryChemistryOrganic Donor BisFunctional MaterialsSynthetic ChemistryPolymer ChemistryBiomolecular EngineeringLinear Chain Compound
Novel, polymeric linear chains of Keggin polyoxometalate units PMnW11O39 linked through Mn-O-W bridges (see picture below) are present in the structure of the title compound 1. The chains alternate with layers of the organic donor bis(ethylenedithio)tetrathiafulvalene (ET). Compound 1 promises interesting material properties resulting from the combination of localized magnetic moments with delocalized electrons.
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