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The copper-promoted oxidative dehydrogenation and inner ring rearrangement of a macrocyclic ligand: the X-ray crystal structure of the resultant complex
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1982
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Polycyclic Schiff BaseEngineeringOrganic ChemistryChemistryHeterocycle ChemistryInorganic Compound15-Membered RingX-ray Crystal StructureOrganometallic CatalysisMacrocyclic LigandInorganic ChemistryBiochemistryCatalysisInorganic SynthesisHeterocyclicNatural SciencesCoordination ComplexCopper-promoted Oxidative DehydrogenationCuii Ion
The (7 + 12 + 7) inner ring system of a polycyclic Schiff base rearranges with accompanying oxidative dehydrogenation to a (15 + 6 + 3) inner ring system on reaction with Cu(ClO4)2.6H2O in the presence of dioxygen in order to accommodate the CuII ion within the 15-membered ring.