Concepedia

High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

Funda Demirhan, Jenny Gun, Ovadia Lev, Rinaldo Poli, Philippe Richard

Journal of the Chemical Society Dalton Transactions · 2002 · 22 citations · 20 references

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Concepts

Abstract

Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH–H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF3)3]+ and [Zn2(O2CCF3)6]2− ions after crystallisation from THF–Et2O.

References

20

Organorhenium Oxides

Wolfgang A. Herrmann, Fritz E. Kühn · Accounts of Chemical Research · 1997 · 303 citations

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Synthesis, Reactivity, and Catalytic Behavior of Iron/Zinc-Containing Species Involved in Oxidation of Hydrocarbons under Gif-Type Conditions

Bharat Singh, Jeffrey R. Long, F.F. De Biani et al. · Journal of the American Chemical Society · 1997 · 132 citations

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Organometallic chalcogen complexes. XXIV. Synthesis, structure, and bonding of [Mo3(h5-C5H5)3S4]+[Sn(CH3)3Cl2]- containing a triangular molybdenum (IV) cluster cation with doubly and triply bridging sulfur atoms

Phillip J. Vergamini, Heinrich Vahrenkamp, Lawrence F. Dahl · Journal of the American Chemical Society · 1971 · 107 citations

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Zinc carboxylate complexes: structural characterisation of some binuclear and linear trinuclear complexes

W. Clegg, Ian R. Little, B. P. Straughan · Journal of the Chemical Society Dalton Transactions · 1986 · 73 citations

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Reaction of Cp*MoCl4 and Cp*WCl4 with H2O, H2S, amines, and hydrazines. Formation of the trioxo anions [Cp*Mo(O)3]- and [Cp*W(O)3]- and the trisulfido anion [Cp*W(S)3]-

Melinda S. Rau, Christine M. Kretz, Gregory L. Geoffroy et al. · Organometallics · 1993 · 65 citations

, , +7