Publication | Closed Access
Asymmetric Inter‐ and Intramolecular Cyclopropanation Reactions Catalyzed by a Reusable Macroporous‐Polymer‐Supported Chiral Ruthenium(II)/Phenyloxazoline Complex
109
Citations
20
References
2010
Year
/Phenyloxazoline ComplexEnantioselective SynthesisAsymmetric Inter‐Broad RangeEngineeringSem ImageOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryAsymmetric CatalysisPolymer ChemistryBiomolecular EngineeringExcellent ReactivityPolymers
Along came poly: A novel macroporous polymer-supported chiral RuII/pheox catalyst (1, see SEM image) afforded excellent reactivity and enantioselectivity in inter- and intramolecular cyclopropanation reactions with a broad range of substrates. The catalyst showed no leaching and could be reused up to 11 times, even after storage.
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