Diphosphorus Complexes as Building Blocks for the Design of Phosphorus‐Containing Organometallic–Organic Hybrid Materials

Abstract

The flexible coordination behavior of Pn ligand complexes in solution is utilized to create unprecedented coordination networks. In combination with ditopic organic linker units, organometallic–organic hybrid compounds are accessible. Depending on the nature of the metal center, metallaparacyclophane-like structures as well as 1D and 2D polymeric arrangements can be achieved.