J- vs. H-type assembly: pentamethine cyanine (Cy5) as a near-IR chiroptical reporter

Vladimir L. Malinovskii, L. D. Patsenker, Robert Häner

Chemical Communications · 2013 · 78 citations · 32 references

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Abstract

The DNA-enabled dimerization of pentamethine cyanine (Cy5) dyes was studied by optical methods. The value of cyanine as a chiroptical reporter using a monomer-to-dimer switch is demonstrated. The specific shape of the CD signal and its high intensity are a result of J-type assembly.

References

32