Theoretical and Synthetic Studies on [Zn₂(η⁵‐C₅Me₅)₂]: Analysis of the ZnZn Bonding Interaction

Abstract

More than 1 g of the dizinc compound [Zn2(η5-C5Me5)2] can be readily obtained in a single preparation. Density functional calculations reveal that the ZnZn bond is relatively strong and derives mainly from interaction between the Zn 4 s orbitals (see picture). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z462175_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.