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A highly robust metal–organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO<sub>2</sub>over CH<sub>4</sub>
61
Citations
45
References
2015
Year
Materials ScienceInorganic ChemistryChemical EngineeringOrganic Material ChemistryEngineeringRobust Metal–organic FrameworkCovalent Bonded FrameworkAromatic 12-Carboxyl LigandSelective AdsorptionRobust MofOrganic ChemistryCoordination PolymerChemistryMetal-organic PolyhedronMolecule-based MaterialMetal-organic FrameworksCd Clusters
A highly robust MOF based on a 12-carboxyl dendritic aromatic ligand and two Cd clusters is successfully synthesized. This activated MOF exhibits high heat of absorption of CO2 and highly selective adsorption of CO2 over CH4. Especially, a new type of topology (hhm-a) is presented.
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