Enhanced Stiffness of Amorphous Polymer Surfaces under Confinement of Localized Contact Loads

Abstract

For contact depths < 200 nm from the free surface of amorphous polymers, the apparent mechanical stiffness is in excess of bulk elastic properties. This enhanced stiffness can be attributed to the dynamic formation of a mechanically distinct interphase at synthetic and biological polymer interfaces. In “glassy” polymers such as polystyrene, this enhanced stiffness is independent of molecular weight, processing route, and environmental conditions. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2089/2007/c2846_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.