Organic Letters · 2003 · 201 citations · 23 references
Chemical EngineeringNovel Vanadium-catalyzed OxidationEngineeringCatalytic AmountIndustrial CatalysisPrimary Hydroxy GroupsHeterogeneous CatalysisOrganic ChemistryThermal CatalysisCatalysisMolecular CatalysisChemistryAtmospheric OxygenCatalytic ProcessChemical KineticsDeoxygenationCatalytic Synthesis
[reaction: see text] Oxidation of alcohols to aldehydes and ketones has been studied in high yields using atmospheric oxygen and a catalytic amount of V2O5 in toluene under heating (ca. 100 degrees C). Secondary alcohols can be chemoselectively converted into ketones in the presence of primary hydroxy groups.
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Kazuya Yamaguchi, Kohsuke Mori, Tomoo Mizugaki et al. · Journal of the American Chemical Society · 2000 · 456 citations
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B. M. Choudary, M. Lakshmi Kantam, Ateeq Rahman et al. · Angewandte Chemie International Edition · 2001 · 266 citations
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