Controlled Self‐Assembly Behavior of an Amphiphilic Bisporphyrin–Bipyridinium–Palladium Complex: From Multibilayer Vesicles to Hollow Capsules

Abstract

Gas-filled: Porphyrin-based amphiphiles can self-assemble into multibilayer vesicles. These vesicles can be converted into hollow capsules and wormlike structures (see picture) by controlling the release rate of methanol encapsulated through changing the heating temperature and pattern.