The first organic cation-radical salt superconductor (T<sub>c</sub>= 4 K) with an organometallic anion: superconductivity, synthesis and structure of κ<sub>L</sub>-(BEDT-TTF)<sub>2</sub>Cu(CF<sub>3</sub>)<sub>4</sub>·TCE - Concepedia

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The first organic cation-radical salt superconductor (T<sub>c</sub>= 4 K) with an organometallic anion: superconductivity, synthesis and structure of κ<sub>L</sub>-(BEDT-TTF)<sub>2</sub>Cu(CF<sub>3</sub>)<sub>4</sub>·TCE

43

Citations

10

References

1994

Year

John A. Schlueter, U. Geiser, Jack M. Williams, H. Hau Wang, W. K. Kwok, J. A. Fendrich, K. Douglas Carlson, Crystal A. Achenbach, J.D. Dudek, Dieter Naumann,

Journal of the Chemical Society Chemical Communications

Superconducting MaterialEngineeringOrganic ChemistryOrganic SuperconductorOrganometallic AnionChemistryInorganic CompoundSuperconductivityHigh Tc SuperconductorsOnset Tc= 4.00Low-temperature SuperconductivityMaterials ScienceInorganic ChemistryHigh-tc SuperconductivityPhysical ChemistryInorganic SynthesisBiomolecular EngineeringCoordination PolymerAmbient Pressure

Abstract

Superconductivity at ambient pressure with onset Tc= 4.00 ± 0.05 K is reported in a unique organic cation-radical salt κL-(ET)2Cu(CF3)4·TCE, [ET = bis(ethylenedithio)tetrathiafulvalene, TCE = 1,1,2-trichloroethane] with the Cu(CF3)4– species being the first Cu3+ and F containing organometallic anion in an organic superconductor.

References

	Year	Citations

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