Publication | Closed Access
Agostic‐type Gold Ligand and Incipient μ<sub>3</sub>‐PPh<sub>2</sub> Coordination in the Au<sub>2</sub>Pt<sub>2</sub>P<sub>6</sub> “Hammock” Skeleton of the Cluster [Au<sub>2</sub>Pt<sub>2</sub>(μ‐PPh<sub>2</sub>)<sub>2</sub>(PPh<sub>3</sub>)<sub>4</sub>][PF<sub>6</sub>]<sub>2</sub>
54
Citations
13
References
1989
Year
Materials ScienceInorganic ChemistryAgostic‐type Gold LigandEngineeringBiochemistryNatural SciencesChemical BondCoordination ComplexCluster ChemistryMolecular ComplexMain Group ChemistryChemistryPh2p BridgeCrystallographyInorganic Compound
Not only bonds between Au and Pt but also between Au and the Ph2P bridge ligands characterize the structure of 2, which is formed in ca. 80 % yield upon reaction of two equivalents of [Au(PPh3)]⊕ with 1 in CH2Cl2.
| Year | Citations | |
|---|---|---|
Page 1
Page 1