Angewandte Chemie International Edition in English · 1989 · 52 citations · 15 references
Natural SciencesChemistryOrganic ChemistryHeterocycle SynthesisHeterocyclic ChemistryHeterocyclic CompoundsOrganic SynthesisMedicinal HeterocyclesTriple Bonds
The title compound can be regarded as an analogue of acetonitrile. It was generated by energetically favorable CO- and CO2-elimination from 2-methyl-1,3,2-dioxaborolane-4,5-dione 1. The CBO skeleton is linear, and a BO triple bond is present. According to the findings of this study, it should be possible to isolate R3CBO compounds with bulky alkyl or aryl residues.
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