Limnology and Oceanography · 1973 · 27 citations · 11 references
Natural SciencesChemistryAnalytical ChemistryElectrochemistryInorganic ChemistryCoordination ChemistryElectroanalytical ChemistryElectrochemical KineticsElectrode KineticsElectrode PotentialsElectrode-electrolyte InterfacesCurrent-potential RelationshipsElectrochemical CharacterizationElectrochemical Equilibrium PotentialEquilibrium In Electrolyte SolutionsFree Energy ChangesPotential - Current CharacteristicsVoltammetric KineticsVoltammetry
The shift in the potential of the zinc stripping current maximum observed in anodic stripping voltammetry is related to the free energy of the reaction between ionic zinc and a complexing anion. The model was tested using the zinc hydroxyl system; the agreement with experimental results was excellent. The findings suggest the existence of the aqueous complex, Zn(OH) 2 o , which has been reported only once before. The stability constant calculated here is in good agreement with the single published value.
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Solutions, minerals and equilibria
H.D. Holland · Geochimica et Cosmochimica Acta · 1966 · 2.4K citations
Stability constants of metal-ion complexes
C. Furlani · Journal of Chromatography A · 1965 · 1.9K citations