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Singly N‐Confused [26]Hexaphyrin: A Binucleating Porphyrinoid Ligand for Mixed Metals in Different Oxidation States
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2011
Year
Inorganic ChemistryDifferent Oxidation StatesMixed MetalsEngineeringBiochemistryNatural SciencesCoordination ComplexOrganic ChemistryTitle PorphyrinoidMolecular ComplexCatalysisRectangular ConformationChemistryBinucleating Porphyrinoid LigandRedox ChemistryInorganic SynthesisUnique Coordination ChemistryInorganic Compound
Mix and match: The title porphyrinoid has been synthesized and shows unique coordination chemistry by incorporating two different metals with different oxidation states (see figure). X-ray crystallography was used to confirm that a rectangular conformation in both mono- and binuclear complexes was retained. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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