Concepedia

1,3‐Dimetallabenzene Derivatives of Niobium or Tantalum

Robert D. Profilet, Phillip E. Fanwick, Ian P. Rothwell

Angewandte Chemie International Edition in English · 1992 · 48 citations · 12 references

DOI

Concepts

Abstract

Insertion of an alkyne into a metal–μ-alkylidyne bond leads to the six-membered dimetal-lacycles 1 and 2 (M = Nb, Ta). Spectroscopic and structural data support their formulation as dimetallabenzene derivatives. cbH = Carbazole.

References

12

Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh<sub>3</sub>)<sub>2</sub>]

Gregory P. Elliott, W.R. Roper, Joyce M. Waters · Journal of the Chemical Society Chemical Communications · 1982 · 278 citations

, , +15

High-oxidation-state molybdenum and tungsten alkylidyne complexes

Richard R. Schrock · Accounts of Chemical Research · 1986 · 255 citations

, , +11

Metathesis of acetylenes by (fluoroalkoxy)tungstenacyclobutadiene complexes and the crystal structure of W(C3Et3)[OCH(CF3)2]3. A higher order mechanism for acetylene metathesis

John H. Freudenberger, Richard R. Schrock, Melvyn Rowen Churchill et al. · Organometallics · 1984 · 189 citations

, , +10

On the trail of metathesis catalysts

Richard R. Schrock · Journal of Organometallic Chemistry · 1986 · 149 citations

, , +5

Metallabenzene: synthesis, structure, and spectroscopy of a 1-irida-3,5-dimethylbenzene complex

John R. Bleeke, Yun Feng Xie, Wei Peng et al. · Journal of the American Chemical Society · 1989 · 110 citations

, , +13