Transition-metal-catalyzed rearrangement of 5-alkynals to γ-alkynylketones and 1-cyclopentenylketones - Concepedia

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Transition-metal-catalyzed rearrangement of 5-alkynals to γ-alkynylketones and 1-cyclopentenylketones

16

Citations

29

References

2005

Year

Ken Tanaka, Kaori Sasaki, Kenzo Takeishi, Koudai Sugishima

Chemical Communications

Chemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryTransition-metal-catalyzed RearrangementAsymmetric Catalysis

Abstract

The transition-metal-catalyzed rearrangement of 5-alkynals to gamma-alkynylketones and 1-cyclopentenylketones was developed using [Rh(P(OPh)3)2]BF4 or Cu(OTf)2 as a catalyst.

References

	Year	Citations

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