Silicifications and associated clay assemblages in the cretaceous marine sediments of southern england

Abstract

Abstract Silicifications and smectite-dominated clay assemblages are associated in the marine Cretaceous sediments of England. Both are neoformed, and have developed at approximately the same time in the host sediment. Two silicification types, opal-CT and α-quartz, have a distribution pattern unrelated to the stratigraphy or lithology of the Lower Greensand, Upper Greensand and Lower Chalk. The petrography of five examples suggest that the two silicification types were both precipitated from the porewaters of their host sediment, and their silica mineralogy and their associated silicate minerals were controlled generally by the silica concentration of the porewaters and more locally by the pH gradients.