Nickel catalyzed Grob fragmentation: ω-dienyl aldehydes synthesis

Masahiko Mori, Masanari Kimura, Yushi Takahashi, Yoshinao Tamaru

Chemical Communications · 2006 · 17 citations · 21 references

Concepts

Abstract

With a proper choice of phosphane ligands, a Ni(cod)2-phosphane catalyst promotes decarboxylative ring-opening reaction of a wide structural variety of cyclic carbonates to give omega-dienyl aldehydes in good yields.

References

21