Concepedia

A σ4, λ5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic estersElectronic supplementary information (RSI) available: experimental procedures for a detailed preparation of complex 4 and cross-coupling experiments. See http://www.rsc.org/suppdata/cc/b2/b203550b/

M. Doux, Nicolas Mézailles, Mohand Melaïmi, Louis Ricard, Pascal Le Floch

Chemical Communications · 2002 · 66 citations · 9 references

DOI

Concepts

Abstract

A palladium(II) complex of a S-P-S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76,500).

References

9

Palladium-Catalyzed Borylation of Aryl Halides or Triflates with Dialkoxyborane:  A Novel and Facile Synthetic Route to Arylboronates

Miki Murata, Takashi Oyama, Shinji Watanabe et al. · The Journal of Organic Chemistry · 1999 · 368 citations

, , +15

Synthesis of pinacol arylboronates via cross-coupling reaction of bis(pinacolato)diboron with chloroarenes catalyzed by palladium(0)–tricyclohexylphosphine complexes

Tatsuo Ishiyama, Kousaku Ishida, Norio Miyaura · Tetrahedron · 2001 · 306 citations · Full text

, , +12

Phosphorus Ylides in the Coordination Sphere of Transition Metals: An Inventory

Hubert Schmidbaur · Angewandte Chemie International Edition in English · 1983 · 273 citations

, , +10

Palladium bis(phosphinite) ‘PCP’-pincer complexes and their application as catalysts in the Suzuki reaction

Robin B. Bedford, Sylvia M. Draper, P. Noelle Scully et al. · New Journal of Chemistry · 2000 · 209 citations

, , +12

Palladium-Catalyzed Borylation of Ortho-Substituted Phenyl Halides and Application to the One-Pot Synthesis of 2,2‘-Disubstituted Biphenyls

Olivier Baudoin, Daniel Guénard, Françoise Guéritte · The Journal of Organic Chemistry · 2000 · 209 citations

, , +8