Angewandte Chemie International Edition in English · 1985 · 86 citations · 20 references
Co AtomsCrystal StructureEngineeringMolecular BiologyCluster 1Computational ChemistryChemistryS LigandsInorganic CompoundNovel Cobalt‐Structure ElucidationBiophysicsMaterials ScienceInorganic ChemistryCluster ScienceCatalysisCrystallographyInorganic SynthesisNatural SciencesCoordination ComplexCrystal StructuresCluster Chemistry
A cube lacking one corner is one way to describe the structure of the cluster 1, which can be prepared from [CoCl2 (PPh3)2] and S(SiMe3)2 in tetrahydrofuran. All Co atoms are coordinated in a distorted tetrahedral fashion, either by three S atoms and the P atom of the PPh3 ligand or by three S ligands and a Cl ligand.
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Heinrich Vahrenkamp, Vernon A. Uchtman, Lawrence F. Dahl · Journal of the American Chemical Society · 1968 · 83 citations