Synthesen in der Depsipetid‐Reihe. 2. Mitteilung. Synthese von Enniatin A

Abstract

Abstract A cyclic hexadepsipeptide containing alternatively N‐methyl‐L‐isoleucine and D‐α‐hydroxy‐isovaleric acid (Fig. 1) has been synthesized. It proved to be identical with Enniatin A, a microbiologically active metabolite isolated in 1947 from Fusarium oxysporum S CHLECHT .