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A Planar {Mn<sub>19</sub>(OH)<sub>12</sub>}<sup>26+</sup> Unit Incorporated in a 60‐Tungsto‐6‐Silicate Polyanion
192
Citations
56
References
2011
Year
Materials ScienceMaterials EngineeringInorganic ChemistryMagnetismMagnetic PropertiesEngineeringMaterial AnalysisMolecule-based MagnetFunctional MaterialsLargest NumberElectrochemical PropertiesChemistryInorganic PolymerInorganic MaterialCrystallographyStructure Mn YellowElectrochemistry
Manganese in large numbers: The largest number of manganese ions ever incorporated in a polyoxometalate (POM) is found in a planar Mn19-oxo-hydroxo magnetic cluster incorporated in a discrete 60-tungsto-6-silicate (see structure Mn yellow, O red/pink). The compound has interesting structural, magnetic, and electrochemical properties.
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