Concepedia

Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z- or E-configured buta-1,3-dien-2-yl esters

Sachin Bhausaheb Wagh, Rai‐Shung Liu

Chemical Communications · 2015 · 31 citations · 26 references

DOI

Concepts

Abstract

Gold-catalyzed synthesis of buta-1,3-dien-2-yl esters by the reaction of propargyl esters with vinylazides is described; the reaction mechanism is postulated to involve a vinyl attack of vinylazides at alkenyl gold carbenes.

References

26

Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids

Alois Fürstner, Paul Davies · Angewandte Chemie International Edition · 2007 · 2.3K citations

, , +16

The Enantioselective Tsuji Allylation

Douglas C. Behenna, Brian M. Stoltz · Journal of the American Chemical Society · 2004 · 553 citations

, , +7

Au<sup>I</sup>‐Catalyzed Tandem [3,3] Rearrangement–Intramolecular Hydroarylation: Mild and Efficient Formation of Substituted Indenes

Nicolas Marion, Silvia Díez‐González, Pierre de Frémont et al. · Angewandte Chemie International Edition · 2006 · 323 citations

, , +10

Mn(III)-Mediated Reactions of Cyclopropanols with Vinyl Azides: Synthesis of Pyridine and 2-Azabicyclo[3.3.1]non-2-en-1-ol Derivatives

Yi‐Feng Wang, Shunsuke Chiba · Journal of the American Chemical Society · 2009 · 302 citations

, , +13

Synthesis of Isoquinolines from α‐Aryl Vinyl Azides and Internal Alkynes by Rh–Cu Bimetallic Cooperation

Yi‐Feng Wang, Kah Kah Toh, Jian‐Yuan Lee et al. · Angewandte Chemie International Edition · 2011 · 301 citations

, , +10