A Supramolecular Approach to Organic Alloys: Cocrystals and Three‐ and Four‐Component Solid Solutions of 1,4‐Diazabicyclo[2.2.2]octane and 4‐X‐Phenols (X=Cl, CH₃, Br)

Abstract

Triple play: The crystallization of 1,4-diazabicyclo[2.2.2]octane (A) with one, two, or three different 4-substituted phenols (B, C, D) leads to cocrystals (for example, AB2, left) or solid solutions (for example, A(B,C,D)2, right). The repeat units of these multicomponent organic solids are supramolecular assemblies of three molecules. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z604830_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.