European Journal of Inorganic Chemistry · 2014 · 30 citations · 32 references
Natural SciencesChemistryCatalysisOrganic ChemistryCarbene ComplexesCatalyst PreparationCatalytic MaterialsCatalytic MechanismsHeterocyclic ChemistryOrganic SynthesisCatalysis By Carbene ComplexesHeterocyclic CatalystsMild Reaction ConditionsMolecular Catalysts
Abstract The platinum‐catalyzed hydrosilylation of amides to afford amines selectively is reported. By using defined platinum/N‐heterocyclic carbene complexes, the reduction of secondary and tertiary amines takes place under mild conditions.
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Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts
István E. Markó, S. Sterin, Olivier Buisine et al. · Science · 2002 · 409 citations