Publication | Closed Access
In Situ Generated (Hypo)Iodite Catalysts for the Direct α‐Oxyacylation of Carbonyl Compounds with Carboxylic Acids
340
Citations
26
References
2011
Year
Carbonyl CompoundsChemical EngineeringEngineeringBiochemistryIndustrial CatalysisNatural SciencesSitu GeneratedIodite CatalystsCatalytic SynthesisOrganic ChemistryCorresponding α-Acyloxycarbonyl CompoundsCatalysisIodite SpeciesChemistryRedox ChemistryTert-butyl HydroperoxideOrganometallic CatalysisBiomolecular Engineering
It′s the iodine: The intra- and intermolecular title reaction is catalyzed by an in situ generated ammonium (hypo)iodite species. Either H2O2 or tert-butyl hydroperoxide (TBHP) can be used as an environmentally benign oxidant and a wide range of substrates react to give the corresponding α-acyloxycarbonyl compounds in good to excellent yields.
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