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Metal catalyzed cross-coupling of aryl and benzyl methyl sulfides: nickel catalyzed C<sub>aryl</sub>–C<sub>sp3</sub> and C<sub>sp3</sub>–C<sub>sp3</sub> bond formations
24
Citations
32
References
2015
Year
Inorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringBenzyl Methyl SulfidesCatalysisMolecular CatalysisChemistryOrganometallic CatalysisSulfur AtomCatalytic SynthesisGood Yields
The nickel catalyzed functionalization of C<sub>Ar</sub>–SMe and C<sub>sp3</sub>–SMe bonds by direct exchange of the sulfur atom with an activated sp<sup>3</sup>-carbon has been developed. The protocol allows the conversion of aryl and benzyl methyl sulfides to trimethylsilylated products in good yields.
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