A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of {Ru(dppe)Cp*}<sub>2</sub>(μ-C<sub>14</sub>) and {Co<sub>3</sub>(μ-dppm)(CO)<sub>7</sub>}<sub>2</sub>(μ<sub>3</sub>:μ<sub>3</sub>-C<sub>16</sub>) - Concepedia

Concepedia

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A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of {Ru(dppe)Cp*}<sub>2</sub>(μ-C<sub>14</sub>) and {Co<sub>3</sub>(μ-dppm)(CO)<sub>7</sub>}<sub>2</sub>(μ<sub>3</sub>:μ<sub>3</sub>-C<sub>16</sub>)

99

Citations

25

References

2004

Year

Michael I. Bruce, Benjamin G. Ellis, M. Gaudio, Paul A. Humphrey, Martyn Jevric, Giovanni Melino, Brian K. Nicholson, G.J. Perkins, Brian W. Skelton, Bronwin Stapleton,

Chemical Communications

Abstract

Elimination of AuX(PR3)(X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)- or C(sp2)-X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by C(n) chains (n up to 16).

References

	Year	Citations

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