Publication | Open Access
Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp<sup>2</sup>)–H bonds at Ir and Rh
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Citations
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References
2014
Year
Inorganic ChemistryChemical EngineeringComputational StudyEngineeringChemical BondHydrogen BondHeterogeneous CatalysisOrganometallic CatalysisCatalysisHydrogenChemistryMetal ControlC–h Bond ActivationPhenylic CKinetic ControlDft StudiesCatalyst Activation
Experimental and DFT studies show the selectivity of C–H bond activation at [MCl<sub>2</sub>Cp*]<sub>2</sub> (M = Ir, Rh) species can be controlled by the choice of metal catalyst, reflecting kinetic control at M = Ir and thermodynamic control at M = Rh.
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