Publication | Open Access
Luminescence characteristics and X‐ray crystal structure of [Cd(bipy)<sub>3</sub>][PF<sub>6</sub>]<sub>2</sub> (bipy = 2,2′‐bipyridine)
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2005
Year
X-ray CrystallographyCrystal StructureEngineeringChemistryLuminescence PropertyLuminescence CharacteristicsLarge Quantum YieldPhotoluminescence CharacteristicsPhotophysical PropertyMaterials ScienceInorganic ChemistryPhotochemistryQuantum ChemistryCrystallographyCrystal Structure DesignNatural SciencesX‐ray Crystal StructureApplied PhysicsMolecular Complex
Abstract The photoluminescence characteristics of the [Cd(bipy) 3 ][PF 6 ] 2 complex are reported. A moderately large quantum yield (φ) of 1.07 × 10 −2 is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by CH···π and CH···F interactions. Copyright © 2005 John Wiley & Sons, Ltd.
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