Field‐Induced Hysteresis and Quantum Tunneling of the Magnetization in a Mononuclear Manganese(III) Complex

Abstract

There is plenty of room at the bottom: A gap in the literature of molecular nanomagnets has been filled with the preparation of the first mononuclear manganese(III) complex exhibiting a slow relaxation of the magnetization, that is, a species with a single slow-relaxing, highly anisotropic MnIII ion, as confirmed by very low-temperature micro-SQUID magnetization and high-field EPR spectroscopic measurements (N blue, O red, Mn purple, Cl green). As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.