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The phenyldimethylsilyl group as a masked form of the hydroxy group
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1984
Year
BiosynthesisEngineeringBiochemistryPhenyldimethylsilyl GroupHydroxy GroupMasked FormNatural Sciencesβ-Phenyldimethylsilyl Carbonyl CompoundsOrganic ChemistryStereoselective SynthesisChemistrySynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
The phenyldimethylsilyl group can be converted in two steps, protodesilylation and peracid-mediated rearrangement, into a hydroxy group with retention of configuration: β-phenyldimethylsilyl carbonyl compounds are thus revealed to be masked aldol products.