Concepedia

β″-(bedt-ttf)<sub>4</sub>[(H<sub>2</sub>O)Fe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·PhCN: the first molecular superconductor containing paramagnetic metal ions

Anthony W. Graham, Mohamedally Kurmoo, Peter Day

Journal of the Chemical Society Chemical Communications · 1995 · 117 citations · 9 references

DOI

Concepts

Abstract

β″-(bedt-ttf)4[(H2O)Fe(C2O4)3]·PhCN [bedt-ttf = bis(ethylenedithio)tetrathiafulvalene] is a superconductor [Tc 8.5(3) K]; from 9–300 K its magnetic susceptibility is dominated by the high-spin FeIII and obeys the Curie–Weiss law (C= 4.375 emu K mol–1, θ=–0.2 K).

References

9

Design of metal-complex magnets. Syntheses and magnetic properties of mixed-metal assemblies {NBu4[MCr(ox)3]}x (NBu4+ = tetra(n-butyl)ammonium ion; ox2- = oxalate ion; M = Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+)

Hiroko Tamaki, Zhuang Jin Zhong, Naohide Matsumoto et al. · Journal of the American Chemical Society · 1992 · 785 citations

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A new ambient-pressure organic superconductor, .kappa.-(ET)2Cu[N(CN)2]Br, with the highest transition temperature yet observed (inductive onset Tc = 11.6 K, resistive onset = 12.5 K)

Aravinda M. Kini, U. Geiser, Hau H. Wang et al. · Inorganic Chemistry · 1990 · 629 citations

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Structure and properties of tris[bis(ethylenedithio)tetrathiafulvalenium]tetrachlorocopper(II) hydrate, (BEDT-TTF)3CuCl4.H2O: first evidence for coexistence of localized and conduction electrons in a metallic charge-transfer salt

Peter Day, Mohamedally Kurmoo, Talal Mallah et al. · Journal of the American Chemical Society · 1992 · 195 citations

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Molecular-based mixed valency ferrimagnets (XR<sub>4</sub>)Fe<sup>II</sup>Fe<sup>III</sup>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>(X = N, P; R =,n-propyl, n-butyl, phenyl): anomalous negative magnetisation in the tetra-n-butylammonium derivative

Corine Mathonière, Simon G. Carling, Yusheng Dou et al. · Journal of the Chemical Society Chemical Communications · 1994 · 187 citations

, , +17

Crystal structures and physical properties of bis(ethylenedithio)-tetrathiafulvalene charge-transfer salts with FeX<sub>4</sub><sup>–</sup>(X = Cl or Br) anions

Talal Mallah, Claire Hollis, Simon G. Bott et al. · Journal of the Chemical Society Dalton Transactions · 1990 · 75 citations

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