Concepedia

Enantiomerically Enriched Tris(boronates): Readily Accessible Conjunctive Reagents for Asymmetric Synthesis

John R. Coombs, Liang Zhang, James P. Morken

Journal of the American Chemical Society · 2014 · 165 citations · 57 references

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Abstract

High Resolution Image Download MS PowerPoint Slide The catalytic enantioselective diboration of vinyl boronate esters furnishes chiral tris(boronates) in a selective fashion. Subsequent deborylative alkylation occurs in a diastereoselective fashion, both for intermolecular and intramolecular processes.

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