Concepedia

Homogeneous Ruthenium Precatalyst for Suzuki–Miyaura Coupling Reaction

Motoi Kawatsura, Kosuke Kamesaki, Mitsuaki Yamamoto, Shuichi Hayase, Toshiyuki Itoh

Chemistry Letters · 2010 · 13 citations · 20 references

DOI

Concepts

Abstract

Abstract Ru(cod)(2-methylallyl)2 was found to catalyze the Suzuki–Miyaura cross-coupling reaction of aryl bromides and aryl iodides with arylboronic acids. The reaction was catalyzed by 10 mol % Ru(cod)(2-methylallyl)2 at 60 °C, and afforded the biaryls in moderate to good yields.

References

20

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Akira Suzuki · Journal of Organometallic Chemistry · 1999 · 2.9K citations

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Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions

Adam F. Littke, Chaoyang Dai, Gregory C. Fu · Journal of the American Chemical Society · 2000 · 1.6K citations

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Synthetic studies via the cross-coupling reaction of organoboron derivatives with organic halides

Akira Suzuki · Pure and Applied Chemistry · 1991 · 437 citations · Full text

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Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling

Gary A. Molander, Belgin Canturk · Angewandte Chemie International Edition · 2009 · 430 citations · Full text

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General Catalysts for the Suzuki–Miyaura and Sonogashira Coupling Reactions of Aryl Chlorides and for the Coupling of Challenging Substrate Combinations in Water

Kevin W. Anderson, Stephen L. Buchwald · Angewandte Chemie International Edition · 2005 · 400 citations · Full text

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