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[{HC(CMeNAr)<sub>2</sub>}<sub>2</sub>Al<sub>2</sub>P<sub>4</sub>] (Ar=2,6‐<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>): A Reduction to a Formal {P<sub>4</sub>}<sup>4−</sup>Charged Species
146
Citations
18
References
2004
Year
Materials ScienceInorganic ChemistryWhiter ShadeEngineeringNatural SciencesProton TransferWhite Phosphorus YieldsMolecular ComplexMain Group ChemistryQuantum ChemistryHydrogenChemistryQuantum Chemical Calculations
A whiter shade of PAl: The reaction of LAlI with white phosphorus yields the first main-group complex [(LAl)2P4] (L=HC(CMeNAr)2, Ar=2,6-iPr2C6H3) containing the {P4}4− moiety, in which two P–P edges of the P4 tetrahedron are opened and each is bridged by a LAl moiety (see structure). The results are supported by quantum chemical calculations.
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